meso-Tetraphenyl-tetrabenzoporphine palladium complex
| Code | Size | Price |
|---|
| CDX-T0083-M025 | 25 mg | £218.00 |
Quantity:
| CDX-T0083-M250 | 250 mg | £1,698.00 |
Quantity:
Prices exclude any Taxes / VAT
Overview
Regulatory Status: RUO
Shipping:
Ambient
Storage:
+4 °C
Documents
Further Information
Alternate Names/Synonyms:
PdPh4TBP; PdTPBP
Appearance:
Deep blue powder.
CAS:
119654-64-7
EClass:
32160000
Form (Short):
liquid
Handling Advice:
Protect from light and moisture.
InChi:
InChI=1S/C60H36N4.Pd/c1-5-21-37(22-6-1)49-53-41-29-13-15-31-43(41)55(61-53)50(38-23-7-2-8-24-38)57-45-33-17-19-35-47(45)59(63-57)52(40-27-11-4-12-28-40)60-48-36-20-18-34-46(48)58(64-60)51(39-25-9-3-10-26-39)56-44-32-16-14-30-42(44)54(49)62-56;/h1-36H;/q-2;+2/b53-49-,54-49-,55-50-,56-51-,57-50-,58-51-,59-52-,60-52-;
InChiKey:
WOKKIHAKMSHWEZ-XJTLWADGSA-N
Long Description:
Chemical. CAS: 119654-64-7. Formula: C60H36N4Pd. MW: 919.392. Synthetic. Phosphorescent probe for measuring oxygen in very low concentrations. Luminescent marker for oxygen and pH in biomedical imaging. Used as sensitizer in the process of photon up-conversion based on triplet?triplet annihilation (TTA). Used as agent for PDT, optical limiters and other types of nonlinear optical materials.
MDL:
MFCD03095471
Molecular Formula:
C60H36N4Pd
Molecular Weight:
919.392
Package Type:
Vial
Product Description:
Phosphorescent probe for measuring oxygen in very low concentrations. Luminescent marker for oxygen and pH in biomedical imaging. Used as sensitizer in the process of photon up-conversion based on triplet?triplet annihilation (TTA). Used as agent for PDT, optical limiters and other types of nonlinear optical materials.
Purity:
>97% (NMR)
SMILES:
C1=CC=C(C=C1)C1=C2C3=C(C=CC=C3)C3=[N]2[Pd++]24[N-]5C1=C1C=CC=CC1=C5C(=C1C5=C(C=CC=C5)C(C(=C5[N-]2C(C2=C5C=CC=C2)=C3C2=CC=CC=C2)C2=CC=CC=C2)=[N]41)C1=CC=CC=C1
Solubility Chemicals:
Soluble in dichloromethane, toluene or acetonitrile.
Source / Host:
Synthetic.
Transportation:
Non-hazardous
UNSPSC Category:
Fluorescent Reagents
UNSPSC Number:
41105331
Use & Stability:
Stable for at least 2 years after receipt when stored at +4°C.
References
(1) S.A. Vinogradov & D.F. Wilson; J. Chem. Soc. Perkin Trans. 2, 103 (1995) | (2) S.A. Vinogradov & D.F. Wilson; Oxygen Transport to Tissue XVIll p597-603 (1997) | (3) J.E. Rogers, et al.; J. Phys. Chem. A. 107, 11331 (2003) | (4) S. Baluschev, et al.; New J. Physics 10; 013007 (2008) | (5) A.Y. Lebedev, et al.; J. Phys. Chem. A. 112, 7723 (2008) | (6) S.M. Borisov, et al.; Anal. Chem. 80, 9435 (2008) | (7) S. Schreml, et al.; Theranostics 4, 721 (2014) | (8) O.S. Kwon, et al.; ACS Nano 10, 1512 (2016) | Photochromic reaction by red light via triplet fusion upconversion: A. Tokunaga, et al.; J. Am. Chem. Soc. 141, 17744 (2019)