D-(+)-Camphoric acid

AdipoGen Life Sciences
Product Code: AG-CN2-0461
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AG-CN2-0461-G0011 g£25.00
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Prices exclude any Taxes / VAT

Overview

Regulatory Status: RUO
Shipping:
Ambient
Storage:
-20°C

Images

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Chemical Structure

Chemical Structure

Further Information

Alternate Names/Synonyms:
(1R,3S)-Camphoric acid; (1R,3S)-1,2,2-Trimethyl-1,3-cyclo-pentanedicarboxylic acid
Appearance:
White powder.
CAS:
124-83-4
EClass:
32160000
Form (Short):
solid
Handling Advice:
Keep cool and dry.
InChi:
InChI=1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m1/s1
InChiKey:
LSPHULWDVZXLIL-LDWIPMOCSA-N
Long Description:
Chemical. CAS: 124-83-4. Formula: C10H16O4. MW: 200.2. Synthetic (originally isolated from Cinnamomum camphora). Chirality inducing agent. Useful tool as resolving agent to separate the isomers and purify racemic mixtures (e.g. DL-lysine) by fractionally crystallizing the product to obtain the pure isomer (e.g. L-lysine). Can also be used as building block. Insect repellent. Stimulator of osteoblast differentiation.
MDL:
MFCD00064937
Molecular Formula:
C10H16O4
Molecular Weight:
200.2
Other data:
Optical Rotation: [alpha]20/D c=1 in MeOH: +46.0° ±2.0°
Package Type:
Vial
Product Description:
Chirality inducing agent. Useful tool as resolving agent to separate the isomers and purify racemic mixtures (e.g. DL-lysine) by fractionally crystallizing the product to obtain the pure isomer (e.g. L-lysine). Can also be used as building block. Insect repellent. Stimulator of osteoblast differentiation.
Purity:
>98% (Titration)
SMILES:
CC1(C)[C@H](CC[C@@]1(C)C(O)=O)C(O)=O
Solubility Chemicals:
Soluble in ethanol, methanol or water.
Source / Host:
Synthetic (originally isolated from Cinnamomum camphora).
Transportation:
Non-hazardous
UNSPSC Category:
Natural Products/Extracts
UNSPSC Number:
12352200
Use & Stability:
Stable for at least 2 years after receipt when stored at -20°C.

References

Die Konstitution des Kamphers und seiner wichtigsten Derivate: O. Aschan, Verlag Friedrich Vieweg & Sohn (1903) | The resolution of dl-lysine: C. P. Berg; J. Biol. Chem. 115, 15 (1936) | Behavioral responses of the pine wood nematode to terpenes: Y. Tominaga, et al.; Agric. Biol. Chem. 48, 519 (1984) | (1R,3S)-Camphoric acid as a building block in supramolecular chemistry: adducts with organic polyamines: M. Choudhury, et al.; Acta Crist. B59, 118 (2003) | Camphoric acid stimulates osteoblast differentiation and induces glutamate receptor expression: S.U. Lee, et al.; Amino Acids 38, 85 (2010) | Spontaneous resolution to absolute chiral induction: pseudo-Kagome type homochiral Zn(II)/Co(II) coordination polymers with achiral precursors: K.K. Bisht & E. Suresh; JACS 135, 15690 (2013) | Binary co-crystals of the active pharmaceutical ingredient 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene and camphoric acid: K.K. Bisht, et al.; Acta Crystallogr. B Struct. Sci. Cryst. Eng. Mater. 70, 63 (2014)