Nickamine

Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride; Chloro[N2-[2-(dimethylamino-kappaN)phenyl]-N1,N1-dimethyl-1,2-benzenediaminato-kappaN1,kappaN2]-nickel

Grey powder.

1033772-47-2

32160000

liquid

Keep cool and dry.Protect from light and moisture.

InChI=1S/C16H20N3.ClH.Ni/c1-18(2)15-11-7-5-9-13(15)17-14-10-6-8-12-16(14)19(3)4;;/h5-12H,1-4H3;1H;/q-1;;+2/p-1

IRLHVNUEEKJBEL-UHFFFAOYSA-M

Chemical. CAS: 1033772-47-2. Formula: C16H20ClN3Ni. MW: 348.5. Synthetic Reagent used as a catalyst for cross-coupling reactions between alkyl halides and carbon nucleophiles. Catalyst for alkyl-alkyl Kumada coupling of secondary alkyl halides, direct alkylation of heterocyclic C-H bonds, Sonogashira coupling of nonactivated alkyl halides, Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles. Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation.

MFCD17015253

C16H20ClN3Ni

348.5

Vial

Reagent used as a catalyst for cross-coupling reactions between alkyl halides and carbon nucleophiles. Catalyst for alkyl-alkyl Kumada coupling of secondary alkyl halides, direct alkylation of heterocyclic C-H bonds, Sonogashira coupling of nonactivated alkyl halides, Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles. Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation.

>97% (NMR)

C[N]1(C)C2=CC=CC=C2N2C3=C(C=CC=C3)[N](C)(C)[Ni]12Cl

Soluble in DMSO, THF, 1,4-dioxane, chloroform, dichloromethane, DMA and toluene. Insoluble in alkanes and water.

Synthetic

Non-hazardous

Biochemical Reagents

12352200

Stable for at least 2 years after receipt when stored at +4°C.